Follow the step below to Create Workflow in Jira

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Click on Jira Icon (Top-left ) > Go to Jira setting (on the left side panel)> Click on Issues> Click on ‘Add Workflow’ button(Top-Right)>Give it a Name> Click on ‘Add’ button.
To Add status in the Workflow
Click on ‘Add Status’ button>Give it a Name>click on ‘Add’ button
To Add Transition between the status
Click on ‘Add Transition’ button>select From and To Status (in the popup)>add a Name and Description> Click on ‘Add‘ button.